WebApr 11, 2024 · Paulson S E, Chung M Y and Hasson A S 1999 OH Radical Formation from the Gas-Phase Reaction of Ozone with Terminal Alkenes and the Relationship between Structure and Mechanism J. Phys. Chem. A 103 8125. Article CAS Google Scholar Criegee R 1975 Mechanism of Ozonolysis Angew. Chem. Int. Ed. 14 745 • Die Einwirkung von Acridiniumsalzen auf kupplungsfähige Substanzen, Dissertation, Univ. Würzburg 1925 • Oxydation ungesättigter Kohlenwasserstoffe mit Blei(4)salzen, Liebigs Ann. Chem. 481,263 (1930) doi:10.1002/jlac.19304810117 • Die Umlagerung der Dekalin-peroxydester als Folge von kationischem Sauerstoff, Liebigs Ann. Chem. 560,127 (1948) doi:10.1002/jlac.19485600106
Criegee oxidation - Wikipedia
WebModifications. Although the classic substrate for the Criegee oxidation are 1,2-diols, the oxidation can be employed with β-amino alcohols, α-hydroxy carbonyls, and α-keto … WebMar 20, 2024 · The process results in Criegee’s molozonides followed by subsequent cleavage and formation of various species including carbonyl hydroperoxides, as shown in Scheme 1. Further scission of these hydroperoxides may lead to grafting as well as to reduction of the polymer chain length [ 22 ]. s windsor shoes
Direct kinetic measurements and theoretical predictions of an ... - PNAS
WebMay 1, 2024 · Arrhenius plots as − R dln k /d(1/ T), where R is the gas constant, k is the rate constant, and T is the temperature. Large Criegee intermediates have many conformational WebAfter more than 70 years since their discovery,Criegee intermediates (CIs) are backatthe forefront of modern chemistry of short-lived reactive intermediates.They play an important role in the mechanistic context of chemical synthesis,total synthesis,pharmaceuticals,and, most importantly,climate-controlling aerosol formation as well as atmospheric … WebReference details. Criegee, R., Angew. Chem., (1975) 87, p.765; Angew. Chem. Int. Ed. Engl., (1975) 14, p.745. s wirdy/vp